J.W.HARRIS CO.INC. -- STAY-CLEAN LIQUID FLUX -- -
===================== Product Identification ===================== Product ID:STAY-CLEAN LIQUID FLUX MSDS Date:04/01/1996 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:J.W.HARRIS CO.INC. Address:10930 DEERFIELD ROAD City:CINCINNATI State:OH ZIP:45242 Country:US Info Phone Num:513-891-2000 Emergency Phone Num:800-424-9300 Resp. Party Other MSDS Num.:MSDS #21 - REV 4/96 Chemtrec Ind/Phone:(800)424-9300 CAGE:27911 === Contractor Identification === Company Name:J. W. HARRIS CO., INC. Address:10930 DEERFIELD ROAD Box:City:CINCINNATI State:OH ZIP:45242-4110 Country:US Phone:513-891-2000 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CHLORIDE CAS:7646-85-7 RTECS #:ZH1400000 < Wt:40. OSHA PEL:1.0 MG/M3 OSHA STEL:2 MG/M3 ACGIH TLV:1.0 MG/M3 ACGIH STEL:2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROGEN CHLORIDE CAS:7647-01-0 RTECS #:MW4025000 < Wt:15. OSHA PEL:7.0 MG/M3 OSHA STEL:NOT LISTED ACGIH TLV:7.5 MG/M3 ACGIH STEL:NOT LISTED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM CHLORIDE CAS:12125-02-9 RTECS #:BP4550000 < Wt:25. OSHA PEL:10.0 MG/M3 OSHA STEL:20 MG/M3 ACGIH TLV:10.0 MG/M3 ACGIH STEL:20 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 < Wt:70. OSHA PEL:NOT LISTED OSHA STEL:NOT LISTED ACGIH TLV:NOT LISTED ACGIH STEL:NOT LISTED Ingred Name:METHANOL CAS:67-56-1 RTECS #:PC1400000 < Wt:5. OSHA PEL:260.0 MG/M3 OSHA STEL:325 MG/M3 ACGIH TLV:262.0 MG/M3 ACGIH STEL:325 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:WARNING: PROTECT YOURSELF AND OTHERS. READ AND UNDERSTAND THIS INFORMATION. FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH. BURNS EYES AND SKIN ON CONTACT. CAN BE FATAL IF SWALLOWED. ZINC CHLORIDE - FUME OR DUST CAN CAUSE DERMATITIS AND CONJUNCTIVITIS. MAY CAUSE RASHES, BOILS, CORNEAL BURN, EPIGASTRIC PAIN, NAUSEA, VOMITING, SHOCK (INTERNAL). HYDROGEN CHLORIDE - CAUSES EYE AND SKIN BURNS. INGESTI ON CAUSES SEVERE BURNS OF MOUTH, ESOPHAGUS AND STOMACH. VAPOR EXTREMELY IRRITATING. AMMONIUM CHLORIDE - PROLONGED BREATHING OF FUMES MAY CAUSE IRRITATION OF RESPIRATORY PASSAGES. METHANOL - INGESTION MAY CAUSE BLINDNESS, (SYMPS OF OVEREXP) Effects of Overexposure:HEALTH HAZARDS (CONT): 100 - 250 ML MAY BE FATAL. SYMPTOMS OF OVEREXPOSURE INCLUDE DIZZINESS, VISUAL IMPAIRMENT, NAUSEA, RESPIRATORY FAILURE, MUSCULAR INCOORDINATION AND NARCOSIS. PROLONGED OR REPEATE D SKIN CONTACT MAY CAUSE DERMATITIS, ERYTHMEA, SCALING AND POSSIBLY SYSTEMIC EFFECTS. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, GIVE PLENTY OF WATER OR MILK. DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY. SKIN: FLUSH WITH WATER. INHALATION: IRRITATES RESPIRATORY SYSTEM - MOVE TO FRESH AIR. EYES: FLUSH WI TH WATER FOR AT LEAST 15 MINUTES. PROMPTLY GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=105.C, 221.F Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE . Fire Fighting Procedures:IF LARGE QUANTITIES ARE INVOLVED IN A FIRE, FIREFIGHTERS SHOULD USE (NIOSH APPROVED - ) SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONFLAMMABLE MATERIAL. WHEN HEATED THE MATERIALS MAY RELEASE ZINC CHLORIDED AND ZINC OXIDE FUMES. THE LIQUID FLUX MAY ALSO RELEASE HYDROGEN CHLORIDE GAS AND WATER VAPOR. NFPA HAZARD SIGNAL: HEALTH - 1 ; STABILITY - 0; FLAMMABILITY - 0; SPECIAL - 0. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL, ABSORB, SWEEP-UP, DISPOSE, FLUSH AREA WITH WATER TO CHEMICAL SEWER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT OF FLUX WITH EYES AND SKIN. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. TRAIN EMPLOYEE TO KEEP HIS HEAD OUT OF THE FUMES. Other Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & THE PRECAUTIONARY LABEL ON PROD. SEE ANSI Z49.1, SAFETY IN WELDING, CUTTING & ALLIED PROCESSES PUBLISHED BY THE AMERICAN WELDING SOCIETY, 550 N.W. LEJEUNE, MIAMI , FL 33126 & OSHA PUBLICATION 2206 (29 CFR 1910) GOVERNMENT PRINTING OFFICE, WASHINGTON, D.C. 20402 FOR MORE DETAILS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. FOR MAXIMUM SAFETY, BE C ERTIFIED FOR AND WEAR A NIOSH APPROVED RESPIRATOR AT ALL TIMES WHEN WELDING OR BRAZING. Ventilation:USE ENOUGH VENTILATION TO KEEP THE FUMES & GASES BELOW TLV'S IN THE WORKER'S BREATHING ZONE & THE GENERAL AREA. SEE ANSI/ASC Z49.1 SECTION 5. Protective Gloves:WELDER'S GLOVES. Eye Protection:ANSI APPRVD CHEM WORKS GOGGS & FULL LGTH FSHLD W/FILTER LENS OF (SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR HEAD & BODY PROT WHICH HELP TO PVNT INJURY FROM SPLASHING, SPKS & FLAME. SEE ANSI Z49.1. THIS MAY INCL ARM PROTECTORS, APRONS, HATS, SHOULDER(SUPP DATA) Supplemental Safety and Health EYE PROT:APPROP SHADE NUMBER (SEE ANSI/ASC Z49.1 - SECTION 4.2). PROVIDE PROT SCREENS & FLASH GOGGLES IF NECESSARY TO SHIELD OTHERS. OTHER PROT EQUIP:PROT, AS WELL AS DARK SUBSTANTIAL CLTHG. ================== Physical/Chemical Properties ================== Vapor Pres:0.75 PSI Spec Gravity:1.224 @ 70F pH:2.0 - 3.0 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID WITH AN "ACIDIC" ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH CYANIDES. Stability Condition to Avoid:STABLE IN CLSD CONTAINERS AT ROOM TEMP UNDER NORM STORAGE & HANDLING CONDITIONS. THIS MAT'L CAN BE CONSIDERED A WEAK ACID. IT CAN BE MILDLY CORROSIVE TO SOME METALS, ESP WHEN HOT. Hazardous Decomposition Products:MAY RELEASE HCL GAS WHEN MIXED W/ ZINC CHLORIDE. IF COMBINED W/ SULFIDES, MAY RELEASE H2S GAS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W ALL FEDERAL, STATE & LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: CORROSIVE LIQUID, N.O.S. (ZINC CHLORIDE SOLUTION). HAZARD CLASS: CLASS 8. ID & PACKING GROUP NUMBER: UN 1760, PG III. ERG GUIDE NUMBER: 60. ===================== Regulatory Information ===================== SARA Title III Information:INDIVIDUAL FLUXES COVERED BY THIS MSDS MAY CONTAIN TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372. REFER TO INGREDIENT SECTION FOR CAS NUMBER FOR EACH CHEMICAL INGREDIENT. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.