SHERWIN WILLIAMS CO -- KRYLON FLUORESCENT SPRAY PAINT, 3106 GREEN -- 8010-00-132-2861
===================== Product Identification ===================== Product ID:KRYLON FLUORESCENT SPRAY PAINT, 3106 GREEN MSDS Date:04/06/1990 FSC:8010 NIIN:00-132-2861 === Responsible Party === Company Name:SHERWIN WILLIAMS CO Address:6830 COCHRAN RD City:SOLON State:OH ZIP:44139-3908 Country:US Info Phone Num:216-292-7400; 800-832-2541 Emergency Phone Num:216-292-7400 CAGE:54626 === Contractor Identification === Company Name:SHERWIN WILLIAMS COMPANY Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115 Country:US Phone:216-566-2902 CAGE:54626 Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10-30% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 10-30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 16.56% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 10-30% OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:N-HEPTANE; (HEPTANE) CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: 10-30% OSHA PEL:500 PPM ACGIH TLV:400 PPM; 500 STEL Ingred Name:VM&P NAPHTHA; (LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)) CAS:64742-89-8 Fraction by Wt: 10-30% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SUPDAT: IS HVR/AIR & MAY SETTLE IN LOW PLACES/TRAVEL OUTWARD TO SOURCE OF IGNIT & FLASHBACK. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: & SAFE HNDLG & EXPOS INFO . TOLUENE CAN CAUSE LIVER & KIDNEY DMG. REPORTS HAVE ASSOC (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: RPTD & PRLNG OCCUP OVEREXP TO SOLV W/PERM BRAIN & NERVOUS SYS DMG. CHRONIC EXPOS TO HEXANE MAY CAUSE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: PERIPHERAL NEUROPATHY. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: IRRIGATION TO INSURE WATER CONTACT W/ENTIRE SURFACE OF EYES & LIDS. CALL MD. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PREC: AWAY FROM HEAT, SPKS, FLAMES & OTHER IGNIT SOURCES. DO NOT STORE NEAR STRONG OXIDIZING CHEMICALS. RTECS #:9999999ZZ Ingred Name:VENT: BE PROVIDED TO KEEP AIR CONTAM CONC LEVELS BELOW ACCEPTABLE CRITERIA. THE FOLLOWING EXPOS CTL TECHNIQUES (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: MAY BE USED TO EFTIVELY MINIMIZE EXPOS: LOC EXHST VENT, ENCLSD SYS DESIGN, PROCESS ISOLATION & REMOTE (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: CTL IN COMBINATION W/APPROP USE OF PERSONAL PROT EQUIP & PRUDENT WORK PRAC. THESE TECHNIQUES MAY NOT (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: NECESSARILY ADDRESS ALL ISSUES PERTAINING TO OPERATIONS, THEREFORE, MFR RECOM CONSULTATION W/EXPERTS (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: TO DETERMINE WHETHER OR NOT PROGRAMS ARE ADEQUATE. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT: SKIN & CLOTHING. WASH THOROUGHLY AFTER HANDLING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INGEST: NOT EXPECTED TO BE HARMFUL UNDER NORM USE CNDTNS. IF ACCIDENTALLY SWALLOWED, BURNS/IRRIT TO MUC MEMB, ESOPHAGUS/GI TRACT CAN RSLT. SKIN/EYES: CAUSES IRRIT. INHAL: MAY BE HARMFUL. LIQ/VAP MAY C AUSE IRRIT OF NOSE, THROAT & LUNGS. CANCAUSE CNS DEPRESS. SIGNS & SYMPS MAY INCL HDCH, DIZZ, NAUS, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: VOMIT, UNCON & ASPHY. PROPANE IS SIMPLE ASPHYXIANT. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY LEAD TO ADDICTION & MAY BE HARMFUL/FATAL. CHRONIC: TOLUENE APPEARS ON THE NAVY LI STING OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO (ING 8) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: DILUTE BY DRINKING LG QTYS OF WATER. IMMED CNTCT POIS CTL CTR/HOSPITAL EMER ROOM FOR ANY OTHER ADDNL TREATMENT DIRECTIONS. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP, PREF MOUTH-T O-MOUTH. CALL MD. SKIN: FLUSH W/PLENTY OF WATER. REMOVE CONTAMD CLTHG. CALL MD IF IRRIT PERSISTS. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. EYELIDS SHOULD BE HELD APART DURING (ING 11) ===================== Fire Fighting Measures ===================== Flash Point:SUPDAT Extinguishing Media:USE DRY CHEMICAL FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. DO NOT INCIN (BURN) CNTNR. AVOID HEAT. KEEP CNTNR < 120F(50C). HIGH TEMPS MAY CAUSE BURSTING. DO NOT PLACE CNTNR ON RADIATOR, STOVE, (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL & REMOVE TO CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD. STORE IN COOL WELL-VENT AREA. DO NOT STORE AT TEMPS > 120F. AVOID RADIATORS, STOVES, DIRECT SUNLIGHT/OTHER HEAT SOURCE. KEEP (ING 12) Other Precautions:USE W/ADEQ VENT. TO AVOID BRTHG VAP/SPRAY MIST, OPEN WINDOWS & DOORS/USE OTHER MEANS SUCH AS EXHST FAN TO ENSURE FRESH AIR ENTRY DURING APPLICATN & DRYING. IF EYE WATERING, HDCH/DIZZ EXPERIENCED, WEAR NIOSH/MSHA APPRVD RESP PROT/LEAVE AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE CRITERIA, USE NIOSH/MSHA APPRVD RESP PROT. RESPS SHOULD BE SELECTED BASED ON FORM & CONCENTRATION OF CONTAMINANTS IN AIR I/A/W OSHA 29CFR 1910.134/OTHER AP PLIC STDS/GUIDELINES. Ventilation:IF AIRBORNE CONTAM ARE GENERATED WHEN MATL IS HEATED/HNDLD, SUFFICIENT VENT IN VOL & AIR FLOW PATTERNS SHOULD (ING 13) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES . Other Protective Equipment:AVOID CONTACT WITH SKIN AND EYES. Work Hygienic Practices:HANLE W/GOOD INDUSTRIAL HYGIENE & SFTY PRACTICES WHICH INCL AVOIDING UNNEC EXPOS & REMOVAL OF MATL FROM EYES, (ING 18) Supplemental Safety and Health % VOLAT (BY WT): 82-84. FL PT: >-4F,-16C; PROPELLANT: <-99F,-73C (EST). EXPLO HAZ: IN DIRECT SUNLIGHT/NEAR OTHER HEAT SOURCES. DO NOT PUNCTURE CNTNR. CONTENTS UNDER PRESS WILL DISCHARGE. AVOID OPEN FL AMES, SPKS, PILOT LIGHTS. DO NOT SMOKE.VAP MAY IGNITE EXPLO. SPRAY MIST/VAP EVAPORATING FROM DEPOSITED FILM (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>-49F,>-45C Vapor Pres:50 PSIG Vapor Density:>1 @ 68F Spec Gravity:0.70-0.74 pH:NEUT Evaporation Rate & Reference:>1 (BUTYL ACETATE=1) Solubility in Water:SLIGHT (@ 68F) Appearance and Odor:LIQUID & LIQUIFIED GAS; HYDROCARBON SOLVENT ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY INCLUDE OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE/PROVINCIAL & FEDERAL REQUIREMENTS. EMPTY CONTAINER MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE CONTAINER TO BU RST VIOLENTLY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.