MALLINCKRODT INC -- IODINE -- 6810-00-262-8579
===================== Product Identification ===================== Product ID:IODINE MSDS Date:06/10/1986 FSC:6810 NIIN:00-262-8579 === Responsible Party === Company Name:MALLINCKRODT INC Address:675 MCDONNELL BLVD Box:5840 City:ST. LOUIS State:MO ZIP:63134 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600 CAGE:37940 === Contractor Identification === Company Name:MALLINCKRODT INC Address:675 MCDONNELL BLVD Box:5840 City:ST. LOUIS State:MO ZIP:63134 Country:US Phone:314-539-1600 CAGE:37940 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT)=14MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL-SEVERELY IRRITATE THE MUCOUS MEMBRANES & RESPIRATORY TRACT. INGEST-SEVERE CORROSIVE GASTROENTERITIS. SKIN-THE CRYSTALLINE FORM OR STRONG SOLUTION ARE SEVERE SKIN IRRITANTS. EYE-VAPORS SEV ERELY IRRITATE THE EYES. CHRONIC: INSOMNIA, CONJUNCTIVITIS, INFLAMMATION OF NASAL MUCOUS, BRONCHITIS, RAPID HEART BEAT. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:INHALE-EXCESSIVE TEARS, RHINITIS, TIGHTNESS IN CHEST, SORE THROAT, HEADACHE, DELAYED PULMONARY EDEMA. INGEST-BURNING SENSATIONS, ABDOMINAL PAIN, DIARRHEA, FEVER, VOMITING, STUPOR, SHOCK. SKIN-LESIONS RESEMBLE THERMAL BURNS. EYE:TEARING, INFLAMMATION OF EYELIDS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS, IMPAIRED RESPIRATORY FUNCTION, OR DISEASE OF THE THYROID, LUNGS, OR KIDNEY MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALE-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS HARD, GIVE OXYGEN. WATCH FOR SIGNS OF PULMONARY EDEMA. INGEST-GIVE WATER/MILK. INDUCE VOMITING IF THERE IS NO MEDICAL HELP. GET MEDICAL ATTENTION. SKIN-REMOVE SOLIED CLOTHES. WIPE OFF EXCESS. WASH WITH SOAP & WATER FOR 15 MIN. EYE-WASH WITH PLENTY OF WATER FOR 15 MIN, LIFTING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CONTACT WITH OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE & DIKE AREA. CLEANUP PERSONNEL REQUIRE PROTECTIVE CLOTHING & RESPIRATORY PROTECTION FROM VAPORS. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. ABSORB W/VERMICULITE, DRY SAND, EARTH OR SIMILAR MATE RIAL FOR DISPOSAL. DO NOT FLUSH TO SEWER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. STORE IN COOL, DRY, VENTILATED AREA AWAY FROM SOURCES OF HEAT OR IGNITION. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:STORE SEPERATELY FROM REACTIVE OR COMBUSTIBLE MATERIALS, AND OUT OF DIRECT SUNLIGHT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED A FULLFACEPIECE CHEMICAL CARTRIDGE RESPIRATOR MAY BE WORN IN GENERAL UP TO 100X THE TLV OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY RESPIRATOR SUPPLIER. SUPPLIED AIR FULLFACEPIECE RESPIRATOR OR AIRLINE HOOD MAY BE WORN. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED. LOCAL EXHAUST VENTILATION IS GENERALLY PREFERRED. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEMICAL SAFETY GOGGLES. Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING, BOOTS, LABCOAT, APRON, COVERALL. EYEWASH FOUNTAIN & QUICK DRENCH FACILITIES IN WORK AREA Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH MATERIAL. WASH HANDS AFTER HANDLING. LAUNDRY CONTAMINATED CLOTHING Supplemental Safety and Health DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. CAUSES SEVERE BURNS. STRONG OXIDIZER. CONTACT WITH OTHER MATERIALS MAY CAUSE FIRE. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:363F,184C Melt/Freeze Pt:M.P/F.P Text:237F,114C Vapor Pres:0.3 Vapor Density:8.8 Spec Gravity:4.98 Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:SLIGHTLY Appearance and Odor:BLUISH-BLACK CRYSTALS; METALLIC LUSTER. PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMMONIA,POWDERED METALS,ALKALI METALS,STRONG REDUCING AGENTS. VIOLENT OR EXPLOSIVE REACTION W/ACETALDEHYDE & ACETYLENE. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED IF INVOLVED IN A FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.