MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION -- METHYL ALCOHOL -- 6810-00-292-9676
===================== Product Identification ===================== Product ID:METHYL ALCOHOL MSDS Date:05/01/1986 FSC:6810 NIIN:00-292-9676 === Responsible Party === Company Name:MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% Other REC Limits:NONE OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT=5628MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE. CHRONIC:MARKED IMPAIRMENT OF VISION AND ENLARGEMENT OF THE LIVER HAS BEEN REPORTED.REPEATED OR PROLONGED EXPOSURE MAY CAUSE SKIN IRRITATION Effects of Overexposure:EYES:IRRITANT,EYE LESION;SKIN:DEFATTING,DRYNESS,CRACKING;SKIN ABSORPTION:SYMPTOMS SIMILAR TO INHALATION;INHALATION:IRRITANT,TOXIC TO NERVOUS SYSTEM & OPTIC NERVE,HEADACHE,DROWINESS,NAUSEA,VOMIT,BLURRE D VISION,BLINDNESS,COMA,DEATH,INGESTION:SYMPTOMS SIMILAR TO INHALATION,CAN CAUSE BLINDNESS.FATAL DOSE=100-125ML Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER.SEE DOCTOR IMMEDIATE;SKIN*REMOVE CONTAMINATED CLOTHING.WASH WITH PLENTY SOAP & WATER IF IRRITATION PERSISTS,SEE DOCTOR;INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.SEE DOCTOR;INGESTION:GIVE 2 GLASSES OF WATER & INDUCE VOMIT IMMEDIATELY.SEE DOCTOR IMMEDIATELY.NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:52F(11C) Autoignition Temp:Autoignition Temp Text:725F Lower Limits:6.7 Upper Limits:36 Extinguishing Media:WATER SPRAY,DRY CHEMICAL,ALCOHOL FOAM,CO*2 Fire Fighting Procedures:USE SCBA WITH FULL FACEPIECE & FULL PROTECTIVE CLOTHING.USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND TO DISPERSE UNIGNITED VAPORS. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR.CAN TRAVE ALONG GROUND A LONG DISTIANCE AND FLASHBACK. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES.VENTILATE.WEAR RESPIRATORY PROTECTION & PROTECTIVE CLOTHING.ABSIRB IN INERT MATERIAL AND PLACE IN APPROPRIATE DISPOSAL CONTAINER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE.OUTSIDE OR DETACHED STORAGE PREFERRED.INSIDE STORAGE SHOULD BE FOR FLAMMABLE LIQUID.SEPARATE FROM OXIDIZING MATERIALS. Other Precautions:STORAGE & USE AREAS SHOULD BE NON-SMOKING.SPARKS-PROOF TOOLS & EXPLOSION-PROOF EQUIPMENT SHOULD BE USED IN THE STORAGE & HANDLING AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY DEVICE APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:LOCAL EXHAUST TO MAINTAIN BELOW TVL. Protective Gloves:RUBBER,NEOPRENE. Eye Protection:GOGGLES (DO NOT WEAR CONTACT LENSES) Other Protective Equipment:RUBBER BOOTS,APRON OR COVERALLS. EYEWASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.REMOVE & LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:148F(64.5C) Melt/Freeze Pt:M.P/F.P Text:-144F(-98C) Vapor Pres:97 Vapor Density:1.1 Spec Gravity:0.8 Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS LIQUID.CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. WILL ATTACK SOME FORMS OF PLASTIC,RUBBER,COATING. MAY REACT WITH METALLIC AL TO FORM HAZ GAS. Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAMES. Hazardous Decomposition Products:CO,CO*2FORMALDHYDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE IN A RCA APPROVED FACILITY.DO NOT FLUSH TO SEWER.COMPLY WITH ALL APPLICABLE FEDERAL,STATE & LOCAL ENVIRINMENTAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.