ALUMINUM COMPANY OF AMERICA -- MAGNESIUM RIBBON -- -
===================== Product Identification ===================== Product ID:MAGNESIUM RIBBON MSDS Date:08/31/1992 FSC:NIIN:Submitter:D DG === Responsible Party === Company Name:ALUMINUM COMPANY OF AMERICA Address:1501 ALCOA BUILDING City:PITTSBURGH State:PA ZIP:15219 Country:US Info Phone Num:412-553-4001 Emergency Phone Num:412-553-4001/412-553-4649(TECHNICAL Preparer's Name:NOT PROVIDED. Chemtrec Ind/Phone:(800)424-9300 CAGE:TO464 === Contractor Identification === Company Name:ALUMINUM COMPANY OF AMERICA Address:1501 ALCOA BUILDING Box:City:PITTSBURGH State:PA ZIP:15219 Country:US Phone:412-553-4001 CAGE:TO464 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-0959 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-0962 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-00-P-4747 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-98-P-6953 CAGE:0X801 Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 Contract Num:MDA414-99-P-3288 CAGE:0X801 Company Name:CHEM SCIENTIFIC, LLC Address:67 CHAPEL STREET Box:UNK City:NEWTON State:MA ZIP:02158 Country:US Phone:617-527-6626 CAGE:TO442 Company Name:NASCO INTL INC., NASCO DIV Address:901 JANESVILL AVE Box:City:FORT ATKINSON State:WI ZIP:53538-0901 Country:US Phone:920-563-2446 Contract Num:MDA414-99-A-0001-0253 CAGE:33089 Company Name:NASCO INTL INC., NASCO DIV Address:901 JANESVILL AVE Box:City:FORT ATKINSON State:WI ZIP:53538-0901 Country:US Phone:920-563-2446 Contract Num:MDA414-99-A-0007-0153 CAGE:33089 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-A-0024-0039 CAGE:63759 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-P-4866 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESIUM METAL CAS:7439-95-4 RTECS #:OM2100000 = Wt:99.8 Other REC Limits:NOT PROVIDED. OSHA PEL:10 MG/M3 MGO FUME ACGIH TLV:10 MG/M3 MGO FUME ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:EXPOSURE TO MAGNESIUM METAL OR OXIDE DUST SHOULD BE A LOW HEALTH RISK BY INHALATION AND SHOULD BE TREATED AS A NUISANCE DUST. EXPOSURE TO MAGNESIUM OXIDE FUME SUBSEQUENT TO BURNING, WELDING, MOLTEN ME TAL WORK, ETC. CAN RESULT IN METAL FUMEFEVER. TEMPORARY SYMPTOMS CAN INCLUDE FEVER, CHILLS, NAUSEA, VOMITING, AND MUSCULAR PAIN. ONSET OF SYMTPOMS OCCURS 4-12 HOURS AFTER EXPOSURE. RECOVERY IS USUALLY COMPLETE IN 24-48 HOURS. MEETING THE EXPOSURE LIMITS OF 10 MG/M3 MGO FUME, 5 MG/M3 (RESPIRABLE) SHOULD PREVENT METAL FUME FEVER FROM OCCURING. Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:EXPOSURE TO MAGNESIUM OXIDE FUME CAN RESULT IN FEVER, CHILLS, NAUSEA, VOMITING, AND MUSCULAR PAIN. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Fire Fighting Measures ===================== Flash Point:NONE. Autoignition Temp:=510.C, 950.F Extinguishing Media:SMOTHER FIRE WITH DRY GRAPHITE/OTHER SUITABLE DRY POWDERS. DO NOT USE FOAM, HALOGENATED EXTINGUISHING AGENTS OR CARBON DIOXIDE. PREVENT WATER OF CONTACTING BURNING/MOLTEN MAGESIUM. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA) AND PROTECTIVE CLOTHING WHEN APPROPRIATE. PROTECT EYES AND SKIN AGAINST FLYING PARTICLES. MANUAL APPLICATION OF WATER SHOULD BE CONDUCTED WITH CARE TO PREVENT CONTACT WITH BURNING OR MOLTEN MAGNESIUM. Unusual Fire/Explosion Hazard:FINE POWDER, THIN SHEETS, CHIPS, AND TURNINGS ARE EASILY IGNITED AND BURN WITH INTENSE HEAT AND BRILLIANT WHITE FLAME. POWDERS MAY FORM EXPLOSIVE MIXTURES WITH AIR. MOLTEN METAL MAY REACT VIOLENTLY ON CONTACT WITH WATER. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SCRAP IN CONTAINERS FOR REMELTING. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. WET, MOIST OR HIGH HUMIDITY STORAGE CONDITIONS WILL LEAD TO CORROSION OF THE PRODUCT. STORE AWAY FROM OTHER COMBUSTIBLES IN METAL CABINET. SCRAP SHOULD BE KEPT DRY PRIOR TO REMELTING OPERATIONS. Other Precautions:NO DATA PROVIDED BY RESPONSIBLE PARTY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE THE EXPOSURE LIMIT IS OR MAY BE EXCEEDED, USE NIOSH APPROVED RESPIRATORY PROTECTION. THE SELECTION OF APPROPRIATE RESPIRATOR (DUST AND FUME RESPIRATOR, ETC.) SHOULD BE BASED ON THE ACTUAL OR POT ENTIAL AIRBORNE CONTAMINANTS AND THEIR CONCENTRATIONS PRESENT. Ventilation:USE WITH ADEQUATE VENTILATION TO MEET EXPOSURE LIMITS. Protective Gloves:FIRE RESISTANT. Eye Protection:APPROPRITE EYE PROTECTION AS NECESSARY. Other Protective Equipment:WEAR APPROPRIATE FIRE-RESISTANT CLOTHING (GLOVES, COVERALLS) WHEN EXPOSING MAGNESIUM RIBBON TO ELEVATED TEMPERATURES (950F) WHICH CAN CAUSE IGNITION. Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY. Supplemental Safety and Health VENDORS P/N: M5-1 OZ. MAGNESIUM METAL RIBBON. ================== Physical/Chemical Properties ================== HCC:F8 Boiling Pt:=1110.C, 2030.F Melt/Freeze Pt:=650.C, ######F Decomp Temp:Decomp Text:NOT PROVIDED. Vapor Pres:NOT APPLICABLE. Spec Gravity:1.74, DENSITY:0.063LB/IN3 pH:NOT APPLICABLE. Viscosity:NOT APPLICABLE. Evaporation Rate & Reference:NOT APPLICABLE. Solubility in Water:NEGLIGIBLE Appearance and Odor:SILVERY/WHITE COLOR SOLID METAL RIBBON, 0.006" THICK BY 1/8" WIDE, NO ODOR. Corrosion Rate:NOT PROVIDED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAGNESIUM WILL REACT WITH WATER AND ACIDS TO RELEASE HYDROGEN; ALSO HAZARDOUS WITH CHLORINE, BROMINE, IODINE, OXIDIZING AGENTS, AND ACIDS. Stability Condition to Avoid:AVOID EXPOSURE TO MOISTURE, HEAT, SPARKS, FLAME. Hazardous Decomposition Products:NO DATA PROVIDED BY RESPONSIBLE PARTY. =================== Toxicological Information =================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:RCRA HAZARDOUS WASTE NO.: NOT FEDERALLY REGULATED. =================== MSDS Transport Information =================== Transport Information:D.O.T SHIPPING NAME, HAZARD CLASS, I.D. NO.: MAGNESIUM METAL (RIBBON), FLAMMABLE SOLID, UN 1869. ===================== Regulatory Information ===================== SARA Title III Information:FOR PURPOSES OF SARA III REPORTING, THIS SUBSTANCE CONTAINS NO INGREDIENTS LISTED ON THE EXTREMELY HAZARDOUS, OR 313 LISTS. FOR PURPOSES OF CERCLA REPORTING, THIS SUBSTANCE CONTAINS NO LISTED INGREDIE NTS. THIS MATERIAL FITS THE EPA HAZARD CATEGORY DEFINITION OF A FIRE HAZARD UNDER SARA SECTION 311, 312. IF FUMES ARE GENERATED DURING PROCESSING, THIS MATERIAL FITS THE EPA HAZARD CATEGORY OF IMMEDIA TE (ACUTE) HEALTH HAZARD UNDER SARA SECTIONS 311, 312. IF MOLTEN, THIS MATERIAL FITS THE EPA HAZARD CATEGORY OF REACTIVE HAZARD UNDER SARA SECTIONS 311, 312. Federal Regulatory Information:COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.