PPG INDUSTRIES INC COATINGS & RESINS GROUP -- DU5 URETHANE HARDENER -- 8010-00F056581
===================== Product Identification ===================== Product ID:DU5 URETHANE HARDENER MSDS Date:09/10/1996 FSC:8010 NIIN:00F056581 === Responsible Party === Company Name:PPG INDUSTRIES INC COATINGS & RESINS GROUP Address:4325 ROSANNA DR Box:9 City:ALLISON PARK State:PA ZIP:15101-5000 Country:US Info Phone Num:412-492-5555/304-843-1300 Emergency Phone Num:304-843-1300/412-492-5555 CAGE:DO542 === Contractor Identification === Company Name:PPG INDUSTRIES INC. COATINGS & RESINS GP Address:4325 ROSEANNA DR PO BOX 9 Box:9 City:ALLISON PARK State:PA ZIP:15101 Phone:412-492-5555 CAGE:DO542 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *98-2* CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 30-<40% Other REC Limits:150 PPM OSHA PEL:710 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ALIPHATIC POLYISOCYANATE, HEXAMETHYLENE DIISOCYANATE POLYMER (HDI POLYMER) *98-2* CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 30-<40% Other REC Limits:1 MG/CUM Ingred Name:ISOPHORONE DIISOCYANATE POLYMER *98-2* CAS:53880-05-0 Fraction by Wt: 20-<30% Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA, C8&10 AROMATIC HYDROCARBON *98-2* CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 5-<10% Ingred Name:1,2,4-TRIMETHYLBENZENE, PSEUDOCUMENE *98-2* CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-<5% ACGIH TLV:25 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INGESTION: HARMFUL. EYES: IRRITATION. SKIN: MODERATE IRRITATION & ABSORPTION. INHALATION: HARMFUL, MAY CAUSE IRRITATION/ALLERGIC RESPIRATORY REACTION IN LUNGS. IRRITATES EYES/NOSE & THROAT. IRRITATION OF THE RESPIRATORY SYSTEM, PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNING SENSATION, ASTHMA-LIKE SYMPTOMS, CHEST TIGHTNESS, WHEEZING, SHORTNESS OF BREATH, COUGHING, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, REDNESS, ITCHING, VISUA L DISTURBANCES, DRYNESS, CRACKING, SWELLING. Medical Cond Aggravated by Exposure:LUNG/BREATHING PROBLEMS. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITIING. GENTLY WIPE OUT INSIDE MOUTH. EYES: REMOVE CONTACT LENSES & FLUSH W/A GENTLE STREAM OF LUKE WARM WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF WATER FOR 15 MINS FOLLOWE D BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OTHER SUPPORT MEASURES AS REQUIRED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:92F Lower Limits:1.6 Extinguishing Media:CO2, DRY CHEMICAL/UNIVERSAL AQUEOUS FILM FORMING FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE & MAY BE USED TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WEAR SCBA & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK. CLOSED CONTAINERS MAY EXPLODE WHEN OVERHEATED. DON'T APPLY TO HOT SURFACES. TOXIC GASES MAY FORM W/HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED W/PROPER RESPIRATORY PROTECTION SHOULD BE PERMITTED. REMOVE SOURCES OF IGNITION. TAKE UP W/SAND/VERMICULITE/NONCOMBUSTIBLE ABSORBENT MATARIAL & PLA CE IN CLEAN, EMPTY CONTAINERS FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. KEEP AWAY FROM HEAT, SPARKS, FLAMES & OTHER SOURCES OF IGNITION. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. DON'T SMOKE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL/FATAL. STORE LARGE AMOUNTS IN BUILDINGS & TO PROTECT FO R STORAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE VAPORS/OVERSPRAY ARE PRESENT, USE A NIOSH APPROVED POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR FOR SPRAYING & UNTIL VAPORS/MISTS ARE GONE. Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP CONCENTRATIONS BELOW EXPOSURE LIMITS. Protective Gloves:IMPERMEABLE/BUTYL RUBBER Eye Protection:CHEMICAL TYPE SPLASH GOGGLES Other Protective Equipment:FULL FACE SHIELD, PROTECTIVE CLOTHING, CHEMICAL IMPERVIOUS EQUIPMENT. Work Hygienic Practices:DON'T REUSE CONTAMINATED CLOTHING, SHOES/GLOVES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:255-351F Vapor Density:>1 Spec Gravity:1.014 Evaporation Rate & Reference:(BUO AC = 100): 87 Solubility in Water:0.3% Appearance and Odor:VISCOUS LIQUID W/A CHARACTERISTIC ODOR Percent Volatiles by Volume:53.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES, STRONG MINERAL ACIDS, STRONG OXIDIZING AGENTS, WATER & ALCOHOLS. Stability Condition to Avoid:HEAT, SPARKS, FLAME & OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CO, CO2, HYDROGEN CYANIDE, LOWER MOLECULAR WEIGHT POLYMER FRACTIONS, TRACES OF ISOCYANATE, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY CONTAINERS SHOULD BE RECYCLED/DISPOSED OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.