J.T. BAKER COMPANY -- MANGANESE DIOXIDE -- -
===================== Product Identification ===================== Product ID:MANGANESE DIOXIDE MSDS Date:10/08/1996 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:J.T. BAKER COMPANY Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:908-859-2151 Emergency Phone Num:908-859-2151 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-98-A-0118-0119 CAGE:59896 Company Name:J T BAKER, DIV OF MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-9343 CAGE:0Z8D6 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Minumum % Wt:90. Maxumum % Wt:100. OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:SUCUTANEOUS MOUSE LD50: 422 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, BLOOD, KIDNEYS. ACUTE: INHALATION: IRRITATION OF UPPER RESPIRATORY TRACT. SKIN CONTACT: IRRITATION. EYES: IRRITATION. INGESTION: CENTRAL NERV OUS SYSTEM DEPRESSION. CHRONIC EFFECTS: NONE IDENTIFIED. Explanation of Carcinogenicity:NONE IDENTIFIED. Effects of Overexposure:EYE :IRRITATION. SKIN: IRRITATION. INHALATION: IRRITATION OF UPPER RESPIRATORY TRACT, NAUSEA, WEAKNESS, CHILLS, LOSS OF APPETITE, MANGANISM. INGESTION: CNS DEPRESSION. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGESTION: IF CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE EXPOSED PERSON TO FRESH AIR. SKIN CONTACT: IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES. EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:N/A. Autoignition Temp:Autoignition Temp Text:N/A. Lower Limits:N/A. Upper Limits:N/A. Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT INCLUDING SCBA. MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIALS, FLAMMABLE MATERIALS OR POWDERED METALS CAN CAUSE FIRE OR EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL IN CLEAN, DRY CONTAINER & COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE AND COMBUSTIBLE MATERIALS. Other Precautions:SAF-T-DATA STORGAE COLOR CODE: ORANGE (GENERAL STORAGE). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:PROPER GLOVES RECOMMENDED. Eye Protection:SAFETY GOGGLES RECOMMENDED. Other Protective Equipment:UNIFORM & APRON RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:N/A. Melt/Freeze Pt:=535.C, 995.F Vapor Pres:N/A. Vapor Density:N/A. Spec Gravity:5.02 pH:N/A. Evaporation Rate & Reference:N/A. Solubility in Water:NEGLIGIBLE (<0.1%) Appearance and Odor:BLACK CRYSTALLINE POWDER. ODORLESS. Percent Volatiles by Volume:N/A. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG REDUCING AGENTS, NITRATES, COMBUSTIBLE MATERIALS, HYDROGEN PEROXIDE, AZIDES , CHLORINE, CHLORATES, CHLORINE TRIFLUORIDE. Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:NONE IDENTIFIED. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOMESTIC (US DOT): PROPER SHIPPING NAME: CHEMICALS, N.O.S. (NON-REGULATED). INTERNATIONA (IMO): PROPER SHIPPING NAME: CHEMICALS, N.O.S. (NON-REGULATED); MARINE POLLUTANTS: NO. AIR (ICAO): PROPER SHIP PING NAME: CHEMICALS, N.O.S. (NON-REGULATED). US CUSTOMS HARMONIZATION NUMBER: 28201000002. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.