FRONTIER OIL AND REFINING COMPANY -- GASOLINE -- 9130-01-055-0816
===================== Product Identification ===================== Product ID:GASOLINE MSDS Date:01/01/1987 FSC:9130 NIIN:01-055-0816 === Responsible Party === Company Name:FRONTIER OIL AND REFINING COMPANY Address:1600 BROADWAY City:DENVER State:CO ZIP:80202 Country:US Info Phone Num:307-634-3551 Emergency Phone Num:307-634-3551 CHEMTREC 800-424-9300 CAGE:0A0Y5 === Contractor Identification === Company Name:FRONTIER OIL AND REFINING COMPANY Address:1600 BROADWAY Box:City:DENVER State:CO ZIP:80202 Country:US Phone:307-634-3551 CHEMTREC 800-424-9300 CAGE:0A0Y5 ============= Composition/Information on Ingredients ============= Ingred Name:MIXTURE OF PETROLEUM HYDROCARBONS (AROMATIC AND PARAFFINIC HYDROCARBONS) Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM TWA GASOLINE ACGIH TLV:300 PPM TWA GASOLINE Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-INHALATION:CENTRAL NERVOUS SYSTEM DEPRESSION, NARCOSIS, UNCONSCIOUSNESS, ASPHYXIATION. EYE:IRRITATION. SKIN:DEFATING, IRRITATION. INGESTION: GI DISTURBANCES, ASPIRATION PNEUMONITIS. CHRONIC: DER MATITIS, ANEMIA, PULMONARY EDEMA, LIVERAND KIDNEY DAMAGE. Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:RESPIRATORY IRRITATION, COUGHING, DIFFICULTY IN BREATHING, NAUSEA, VOMITING, FATIGUE, BLURRED VISION, DIZZINESS, HEADACHES, UNCONSCIOUSNESS, EYE IRRITATION, REDNESS, DRY SKIN. Medical Cond Aggravated by Exposure:SKIN AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-50F,-46C Lower Limits:<1% Upper Limits:8% Extinguishing Media:USE CARBON DIOXIDE, FOAM, HALON OR DRY CHEMICAL. USE WATER FOG TO COOL SRROUNDING CONTAINERS. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:MINOR: ABSORB MATERIAL WITH CLAY, VERMICULITE, OR SIMILAR ABSORBENT MATERIAL. PLACE IN DISPOSAL CONTAINERS. MAJOR: DIKE & CONTAIN SPILL. ELIMINATE SOURCES OF IGNITION. SHUT OFF LEAKS. REMOVE LIQUID BY VACUUM OR ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, VENTILATED WORK AREA. KEEP CONTAINERS CLOSED WHEN NOT IN USE. FLAMMABLE LIQUID; EMPTY CONTAINERS CAN BE HAZARDOUS. Other Precautions:EXTREMELY FLAMMABLE LIQUID AND VAPOR. HIGHLY VOLATILE. VAPOR MAY CAUSE FLASH FIRE. VAPORS MAY SPREAD LONG DISTANCES AND IGNITE. KEEP AWAY FROM HEAT, SPARKS, AND FLAME. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR. AIR-SUPPLIED OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED. Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED. AVOID OPEN ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS. Protective Gloves:NEOPRENE, NITRILE, OR POLYVINYL ALCOHOL Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT. WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:B.P. Text:85.0F,29.4C Melt/Freeze Pt:M.P/F.P Text:<-76F,<-60C Vapor Pres:275-475MMH Vapor Density:>1 Spec Gravity:O.70-0.77 Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:INCOLUBLE Appearance and Odor:WATER WHITE TO STRAW YELLOW LIQUID, GASOLINE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRRONG ACIDS & ALKALIS, AND HALOGENS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.