SHERWIN-WILLIAMS CO -- B2WY111, SHER-CLAD EXTERIOR ACRYLIC LATEX (SUPDAT) -- 8010-00N075574
===================== Product Identification ===================== Product ID:B2WY111, SHER-CLAD EXTERIOR ACRYLIC LATEX (SUPDAT) MSDS Date:08/07/1996 FSC:8010 NIIN:00N075574 === Responsible Party === Company Name:SHERWIN-WILLIAMS CO Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-566-2902 Emergency Phone Num:216-566-2917 CAGE:54636 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 7% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE; (CRISTOBALITE) CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0.4% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST Ingred Name:CLAY (KAOLIN); (KAOLIN) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:SILICATE, MICA; (MICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 3% OSHA PEL:20 MPPCF; Z-3 ACGIH TLV:3 MG/M3 RDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 14% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SUPDAT:ANTICIPATED TO BE CARCINOGEN. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. RTECS #:9999999ZZ Ingred Name:OTHER PREC:THE APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:FRACTION). KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:RESP PROT:BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM THIS PROD, UNDERLYING PAINT, OR THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL AND/OR SKIN OR EYE CONT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW REC FOR PROPER USE, VENT, & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN & UPPER RESP SYS. IN CON TINUED AREA VAPS IN HIGH CONC MAY CAUSEHDCH, NAUS/DIZZ. SIGNS & SYMPS OF OVEREXP:REDNESS & ITCHING OR (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, (SUPDAT) Effects of Overexposure:HLTH HAZ:BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC:LONG TERM EXPOS TO HIGH LEVS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING/ABRADING DRY FILM, MAY CAUSE LUNG DMG (SILICOSIS) & POSSIBLY CANCER. RATS EXPOS TO TITANIUM DIOXIDE DUST @ 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS (ING 8) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP AND WATER. REMOVE CONTAMD CLTHG & LAUNDER BEFORE REUSE. EYES:FLUSH WITH LARGE AMOUNTS OF WAT ER FOR AT LEAST 15 MINUTES. GET MEDICALATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. Other Precautions:THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE PRESENT @ HAZ LEVS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED IN INGRED SECTION, (ING 9) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN INGRED SECTION. WHEN SANDING/ABRADING DRIED FI LM, WEAR DUST/MIST RESP APPRVD (ING 12) Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS IN INGRED SECTION IS MAINTAINED BELOW APPLIC EXPOS (ING 13) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR TRADE NAME/PART NO:FLAT HOUSE PAINT, TINTING WHITE. FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLAN OF CARCIN:1994:ANTIC TO BE CARCIN. SILICA, CRYST ALLINE-CRISTOBALITE:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994: (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Density:HVR/AIR Spec Gravity:1.30 VOC Pounds/Gallon:77 pH:9.5 VOC Grams/Liter:.64 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:64 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD IS NOT HAZARDOUS AS DEFINED UNDER RCRA 40 CFR 261. INCINERATE IN APPRVD FACILITY. DO NOT INCINERATE CLOSED CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS REGARD ING POLLUTION. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.