BDH INC -- SODIUM HYDROXIDE -- 6810-00-077-8570
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE MSDS Date:09/21/2000 FSC:6810 NIIN:00-077-8570 Status Code:A === Responsible Party === Company Name:BDH INC Address:350 EVANS AVE City:TORONTO, ONTARIO, CANADA Info Phone Num:416-255-8521/416-201-6383 Emergency Phone Num:416-201-6383 (24 HR.) Preparer's Name:TECHNICAL AFFAIRS DEPT. CAGE:38445 === Contractor Identification === Company Name:BDH INC Address:350 EVANS AVE Box:City:TORONTO, ONTARIO, CANADA Phone:416-255-8521/416-201-6383 CAGE:38445 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 = Wt:100. OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OF SODIUM HYDROXIDE WILL CAUSE BURNS TO THE NOSE, THROAT & LUNGS. CONTACT W/ EYES WILL CAUSE IRRITATION OR SEVERE BURNS. IN SEVERE CASES, ULCERATION & PERMANENT BLINDNESS MAY OCCUR. SKIN CONTACT WILL CAUSE SEVERE BURNS W/ DEEP ULCERATION & PENETRATION TO THE DEEPER LAYERS WILL OCCUR. INGESTION MAY CAUSE SEVERE PAIN, BURNING OF THE MOUTH, THROAT & ESOPHAGUS, VOMITING, DIARRHEA, COLLAPSE & POSSIBLE DEATH. CHRONIC: TISSUE DESTRUCTION. Explanation of Carcinogenicity:NO INFORMATION AVAILABLE. Effects of Overexposure:ACUTE: INHALATION OF SODIUM HYDROXIDE WILL CAUSE BURNS TO THE NOSE, THROAT & LUNGS. THE ONSET OF THESE EFFECTS MAY BE DELAYED. CONTACT W/ EYES WILL CAUSE IRRITATION OR SEVERE BURNS DEPENDING ON THE C ONCENTRATION & DURATION OF EXPOSURE. IN SEVERE CASES, ULCERATION & PERMANENT BLINDNESS MAY OCCUR. SKIN CONTACT WILL CAUSE SEVERE BURNS W/ DEEP ULCERATION & PENETRATION TO THE DEEPER LAYERS WILL OCCUR. CORROSION WILL CONTINUE UNTIL SODIUM HYDROXIDE IS REMOVED. INGESTION MAY CAUSE SEVERE PAIN, BURNING OF THE MOUTH, THROAT & ESOPHAGUS, VOMITING, DIARRHEA, COLLAPSE & POSSIBLE DEATH. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH THE CONTACTED AREA W/ LUKEWARM RUNNING WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING, TAKING CARE NOT TO SPREAD THE CHEMICAL. EYE: FLUSH THE CONTAMINAED EYE(S) FOR AT LEAST 15 MINUTES W/ LUKEWARM RUNNING WATER, HOLDING THE EYELIDS OPEN. INHALATION: REMOVE VICTIM TO FRESH AIR. ASSIST WITH BREATHING SUPPORT MEASURES AS NEEDED. INGESTION: RINSE MOUTH THOROUGHLY WITH WTER . DO NOT INDUCE VOMITING. HAVE VICTIM DRINK 200-400 MO OF WATER. ASSIST WITH BREATHING AS NEEDED. SEEK MEDICAL ATT'N FOR ALL ROUTES OF EXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE AN EXTINGUISHER APPROPRIATE TO THE SURROUNDING MATERIAL THAT IS BURNING. SODIUM HYDROXIDE AND ITS SOLUTIONS WILL NOT BURN OR SUPPORT COMBUSTION. Unusual Fire/Explosion Hazard:REACTION OF SODIUM HYDROXIDE WITH A NUMBER OF COMMONLY ENCOUNTERED MATERIALS CAN GENERATE SUFFICIENT HEAT TO IGNITE NEARBY COMBUSTIBLE MATERIALS. DO NOT LET WATER COME INTO CONTACT WITH THE SODIUM HYD ROXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:BEFORE DEALING WITH SPILLAGES TAKE NECESSARY PROTECTIVE MEASURES, INFORM OTHERS TO KEEP AT A SAFE DISTANCE AND, FOR FLAMMABLE MATERIALS, SHUT OFF ALL POSSIBLE SOURCES OF IGNITION. TRANSFER CAREFULLY I NTO CONTAINER AND ARRANGE REMOVAL BY DISPOSAL COMPANY. WASH SITE OF SPILLAGE THOROUGHLY WITH WATER AND DETERGENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN SUITABLE LABELLED CONTAINERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE AND WHEN EMPTY. PROTECT FROM DAMAGE. STORE AWAY FROM INCOMPATIBLE MATERIAL. AVOID GENERATING DUST. FOLLOW ROUTINE SAFE HANDLING PROCEDURES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED RESPIRATOR, FUME HOOD AS APPROPRIATE. Ventilation:MECHANICAL VENTILATION (DILUTION & LOCAL EXHAUST). USE A CORROSION RESISTNT VENTILATION SYSTEM. EXHAUST DIRECTLY OUTSIDE. Protective Gloves:RUBBER, NEOPRENE, NITRILE, PVC OR EQUIVALENT. Eye Protection:CHEMICAL SAFETY GOGGLES OR FACE SHIELD. Other Protective Equipment:PLASTIC APRON, SLEEVES AND BOOTS AS APPROPRIATE. Supplemental Safety and Health PRODUCT CODES: ACS816, B10252, B30167, B45212, K92768, SX0593, XX0443, 006482, 0064825B, 00648264, 0064826C, SX0593. ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:=1390.C, 2534.F Melt/Freeze Pt:=318.C, 604.4F Vapor Pres:1.0 MMHG @739C Spec Gravity:2.13 pH:12(0.05% W/W Appearance and Odor:WHITE HYGROSCOPIC, PELLETS; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, METALS, ORGANOHALOGEN COMPOUNDS, NITRO, CHLORO ORGANIC COMPOUNDS, PEROXIDES, FLAMMABLE LIQUIDS, CHLOROFORM/METHANOL MIXTURES. Stability Condition to Avoid:NORMALLY STABLE, RAPIDLY ABSORBS CARBON DIOXIDE FROM THE AIR. Hazardous Decomposition Products:NA2O ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW ALL FEDERAL, PROVINCIAL AND LOCAL REGULATIONS FOR DISPOSAL. USE ONLY LICENSED DISPOSAL AND WASTE HAULING COMPANIES. DISPOSAL OF SMALL AMOUNTS OF SPILLED MATERIAL MAY BE HANDLED AS DESCRIBED UND ER "LEAK OR SPILL CLEANUP". LARGE SPILLS MUST BE DEALT WITH SEPARATELY AND MUST BE HANDLED BY QUALIF IED DISPOSAL COMPANIES. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.