GENERAL CHEMICAL CORP -- ZINC ACETATE -- 6810-00N053070
===================== Product Identification ===================== Product ID:ZINC ACETATE MSDS Date:09/01/1986 FSC:6810 NIIN:00N053070 === Responsible Party === Company Name:GENERAL CHEMICAL CORP Address:CN 1829 City:MORRISTOWN State:NJ ZIP:07960-1829 Country:US Info Phone Num:204-455-5630 Emergency Phone Num:201-455-3700 CAGE:0AU44 === Contractor Identification === Company Name:GENERAL CHEMICAL CORPORATION Address:90 EAST HALSEY ROAD Box:City:PARSIPPANY State:NJ ZIP:07054 Country:US Phone:973-515-1840 CAGE:0AU44 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC ACETATE, DIHYDRATE CAS:5970-45-6 RTECS #:ZG8750000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT): 2460 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: WILL IRRITATE MUCOUS MEMBRANES, CAUSE COUGHING, WEAKNESS, GENERALIZED ACHING, CHILLS, FEVER, NAUSEA. SUCH SYMPTOMS ARE USUALLY TRANSITORY. DUST/MIST MAY IRRITATE CAUSING COUGHING OR DIFFICULTY IN BREATHING. INGEST: IRRITATION OR CORROSION OF THE ALIMENTARY TRACT W/PAIN, EMESIS, ETC. TOXICITY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: & TOXIC ACTIONS ARE SIMILAR TO THOSE OF COPPER SALTS. SKIN: ACTS AS MILD IRRITANT. CHRONIC: NONE KNOWN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: PROMPTLY FLUSH W/WATER CONTINUING FOR AT LEAST 15 MIN. IF SYMPS PERSIST, GET MED ATTN. SKIN: WASH W/SOAP & WATER, THEN FLUSH W/WATER UNTIL ALL CHEM IS REMOVED. REMOVE CONTAMD CLTHG & WASH BEFORE REUSE. INHAL: IMMED REMOVE TO FRESH AIR. IF BRTHG W/DFCLTY, GIVE OXYGEN IF QUALIFIED OPERATOR IS AVAIL. INGEST: IF CONSCIOUS, IMMED INDUCE VOMIT BY GIVING 2 TO 4 GLASSES OF WATER & TOUCHING (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:IF INVOLVED IN A FIRE, FLOOD WITH WATER. ANY STANDARD AGENT MAY BE USED. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . KEEP FIRE-EXPOSED CONTAINERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:THE POSSIBILITY OF HAZARDOUS DECOMPOSITION PRODUCTS EXISTS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP, AVOIDING DUSTY CONDITIONS, & COLLECT IN CONTAINER (E.G. FIBERBOARD) & CLOSE. STORE FOR LATER USE OR DISPOSAL IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. FINISH CLEAN-UP WITH WATER . Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE OF LOW FIRE RISK IN TIGHTLY CLOSED CONTAINERS. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID BREATHING DUST, MIST OR FUMES. USE WITH ADEQUATE VENTILATION. DO NOT WEAR CONTACT LENSES SHOULD DUSTY/MISTY CONDITIONS ARISE OR IF SOLUTION IS BEING HA NDLED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR DUSTY/MISTY CONDITIONS, USE DUST/MIST RESP APPROVED BY NIOSH/MSHA. FOR FUMES OF ZINC OXIDE WHICH MIGHT BE FORMED AT HIGH TEMPERATURES, USE NIOSH/MSHA APPROVED SCBA OR SUPPLIED-AIR RESPIRATOR. Ventilation:PROVIDE LOCAL EXHAUST IF DUSTY, MISTY/FUMING CNDTNS PREVAIL. NATURAL EXHAUST SHOULD BE ADEQ IN ABSENCE OF THESE CNDTNS. Protective Gloves:RUBBER GLOVES. Eye Protection:CHEMICAL SAFETY GOGGLES. Other Protective Equipment:TO MINIMIZE CONTACT WEAR FULL WORK CLOTHING INCLUDING LONG-SLEEVED SHIRT & TROUSERS, SHOES. Work Hygienic Practices:FOLLOW GOOD PERSONAL HYGIENE & HOUSEKEEPING PRACTICES. Supplemental Safety and Health PH: ABOUT 5-6 (5% AQ SOLN @ 25C:6-7). SOL IN H*2O: 30% (FOR DIHYDRATE AT AMBIENT). CNDTNS(STAB): IS COMPLETE @ 350-400C. WHEN HEATED BELOW ITS MELTING POINT (1975C), ZNO SUBLIMES, EMITTING TOX FUMES. FIRST AID PROC: BACK OF THROAT W/FINGER. CALL MD. GIVE MILK/EGG WHITES W/WATER. KEEP WARM & QUIET. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:459F,237C Spec Gravity:1.735 (H*2O=1) pH:SUPDAT Solubility in Water:SUPDAT Appearance and Odor:WHITE CRYSTALLINE POWDER/GRANULES, SLIGHTLY EFFLORESCENT; FAINT ACETIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS: MAY REACT W/EXPLOSIVE VIOLENCE. WATER-REACTIVE MATLS SUCH AS OLEUM: STRONG EXOTHERMIC REACTION. Stability Condition to Avoid:HEATING CAUSES MATL TO LOSE WATER AT 212F; CAUSES MATL TO START TO DECOMPOSE TO ZNO @ APPROX 250C. THIS PROCESS (SUPDAT) Hazardous Decomposition Products:NOT KNOWN. HOWEVER, IN A FIRE, EXPECT AT LEAST CO, CO*2 WITH ZINC OXIDE AS RESIDUE, GIVING OFF TOX FUMES OF ZINC OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL OF WASTE ZINC ACETATE MAY BE SUBJECT TO FED, STATE & LOC REGS. USERS SHOULD REVIEW THEIR OPERATIONS IN TERMS OF APPLIC LAWS & REGS, THEN CONSULT W/APPROP REGULATORY AGENCIES BEFORE DISCHARGIN G OR DISPOSING OF WASTE MATERIAL. NOT AHAZ WASTE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.