CRAWFORD LABORATORIES, INC -- EPOXY -- 8010-01-441-5911
===================== Product Identification ===================== Product ID:EPOXY MSDS Date:03/07/1996 FSC:8010 NIIN:01-441-5911 Status Code:A === Responsible Party === Company Name:CRAWFORD LABORATORIES, INC Address:4165 SOUTH EMERALD AVENUE City:CHICAGO State:IL ZIP:60609 Country:US Info Phone Num:312-376-7132 Emergency Phone Num:(800)424-9300 Preparer's Name:DAVID SCHMETTERER Chemtrec Ind/Phone:(800)424-9300 CAGE:5V430 === Contractor Identification === Company Name:CRAWFORD LABORATORIES, INC Address:4165 SOUTH EMERALD AVENUE Box:City:CHICAGO State:IL ZIP:60609 Country:US Phone:312-376-7132 CAGE:5V430 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE CAS:78-93-3 RTECS #:EL6475000 = Wt:14. OSHA PEL:100 PPM ACGIH STEL:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:100 SOLVENT CAS:64742-95-6 RTECS #:WF3400000 = Wt:1.9 OSHA PEL:50 PPM ACGIH STEL:50 PPM Ingred Name:EPOXY RESIN CAS:25085-99-8 = Wt:21. Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:3.4 OSHA PEL:100 PPM ACGIH STEL:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILICONE DIOXIDE CAS:14808-60-7 RTECS #:VV7330000 = Wt:17. OSHA PEL:0.1 MG/M3 Ingred Name:GREEN PIGMENT CAS:14302-13-7 RTECS #:GL7500000 Fraction by Wt: 0.098% Ingred Name:DILUENT 8 CAS:68609-97-2 Code:F = Wt:2.3 Ingred Name:DIATOMACEOUS EARTH, FLUX-CALCINED CAS:68855-54-9 = Wt:5.7 ===================== Hazards Identification ===================== Effects of Overexposure:OVEREXPOSURE MAY PRODUCE VARIOUS EFFECTS, INCLUDING: 1-ACUTE TOXICITY, RESULTING IN HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF CONSCIOUSNESS. 2- SEVERE EYE IRRITATION POSSIBLY RESULTING IN PERMANENT DAM AGE. 3- IRRITATED MUCOUS MEMBRANES. 4- VOMITTING DUE TO INGESTION. 5- DEFATTING AND DRYING OF THE SKIN. 6- SENSITIZATION AFTER REPEATED CONTACT. ======================= First Aid Measures ======================= First Aid:EYE CONTACT-FLUSH WITH LUKEWARM LOW PRESSURE WATER FOR 15 MINUTES. OCCASIONALLY LIFTING EYELIDS. GET MEDICAL ATTENTION. -INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DI FFICULT. GIVE ARTIFICAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. KEEP VICTIM WARM AND COMFORTABLE. INGESTION: IF SWALLOWED, CALL PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITTIN ON INSTRUC TIONS OF PHYSICIAN. IF VOMITTING OCURS SPONTANEOULSY, KEEP HEAD BELOW HIPS TP PREVENT ASPIRATION OF LIQUID INTO LUNGS. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. -* ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=-5.4C, 22.F 22F Lower Limits:1.4 Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL. - Fire Fighting Procedures:WATER MAY BE USED TO KEEP EXPOSED CONTAINERS COOL, AND TO KEEP FLAMMABLE STRUCTURES WET. DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION BECAUSE HAZARDOUS DECOMPOSITION PRODUCTS MAY BE PRESENT. - Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:FLAMMABLE. ELIMANATE ALL IGNITION SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:TREAT AS A HAZARDOUS- FLAMMABLE MATERIAL. Other Precautions:ANY PROPOSED USE OF THIS PRODUCT IN ELEVATED TEMPERATURE PROCESSES SHOULD BE THOROUGHLY EVALUTED TO ASSURE THAT SAFE OPERATING CONDITIONS ARE ESTABLHISHED AND MAINTAINED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IMPORTANT MUST PROVIDE ADEQUATE VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS BELOWTHE ESTABLISHED TLV LIMIT AS GIVEN BY OSHA. IN MORE CONFINED AREAS A KIOSH-MSHA APPROVED RESPIRATOR EEQUIPPED WITH OR GANIC VAPOR CARTRIDGE SHOULD BE WORN. - Ventilation:MUST PROVIDE ADEQUATE VENTILATION. - Protective Gloves:USE RUBBER GLOVES. - Eye Protection:WEAR APPROVED SAFETY GOGGLES AND/OR FACE SHEILD. - Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:>79.4C, 175.F B.P. Text:175-344F Vapor Density:>AIR Evaporation Rate & Reference:3.76 X N-BUTYL ACETATE Solubility in Water:SLIGHT Appearance and Odor:GREEN/SOLVANT ODOR Percent Volatiles by Volume:34 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALAALIES. - Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, AND INCOMPATIBILTIES ABOVE. - Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC GASES. =================== Toxicological Information =================== Toxicological Information:SKIN CONTACT: FLUSH WATER WHILE REMOVING CONTAMINATED CLOTHNG. WASH WITH SOAP AND WATER. DO NOT REUSE CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. ===================== Ecological Information ===================== Ecological:EPA HAZARDOUS WASTE CODE: D001 CHARACTERISTICS:IGNITABLE *HOT ORGANIC CHEMICAL VAPORS/MISTS SUSCEPTIBLE-SUDDEN SPONTANEOUS COMBUSTION WH-MIXED W/AIR.IGNITION MAY OCCUR@TEMPERATURES BELOW PUBLISHED IN LITERATURE AS"AUTOIGNITION"/"IGNITION"TEMPERATURES.IGNITION TEMPERATURES DECREASE W/INCREASING VAPOR VOLUME&VAPOR/AIR CONTACT TIME&INFLUENCED BY PRESSURE CHANGES.IGNITION MAY OCCUR@TYPICAL ELEVATED T EMPERATURE PROCESS CONDTIONS,ESPECIALLY IN PROCESS OPERATING UNDER VACUUM IF SUBJECTED-SUDDEN INGRESS OF AIR/OUTSIDE PROCESS.EQUIPMENT OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF VAPORS/MIST S-ATMOSHERE OCCURS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT LOCAL, STATE AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL FACILITY. =================== MSDS Transport Information =================== Transport Information:KNOW APPLICABLE D.O.T. REGULATIONS BEFORE ATTEMPING TO TRANSPORT THIS MATERIAL . ===================== Regulatory Information ===================== SARA Title III Information:METHYL ETHYL KETONE State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.