BASF CORP CHEMICALS DIV -- ZEREX ANTIFREEZE, 547278 -- 6850-00N027102
===================== Product Identification ===================== Product ID:ZEREX ANTIFREEZE, 547278 MSDS Date:05/06/1988 FSC:6850 NIIN:00N027102 === Responsible Party === Company Name:BASF CORP CHEMICALS DIV Address:100 CHERRY HILL RD City:PARSIPPANY State:NJ ZIP:07054 Country:US Info Phone Num:201-316-3000 Emergency Phone Num:201-316-300O;800-424-9300(CHEMTREC) CAGE:FO656 === Contractor Identification === Company Name:BASF CORP CHEMICALS DIV Address:100 CHERRY HILL RD City:PARSIPPANY State:NJ ZIP:07054 Phone:(201) 316-3000 CAGE:FO656 Company Name:BASF CORPORATION Address:Box:13528 City:RESEARCH TRIANGLE PARK State:NC ZIP:27709 Country:US Phone:919-547-2000 CAGE:1T774 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III). LD50: (ORAL, RAT) 13.8 ML/KG. CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 94% OSHA PEL:50 PPM, C ACGIH TLV:50 PPM, C, VAPOR EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PHOSPHATES CAS:7756-11-4 Fraction by Wt: <2% Ingred Name:SODIUM (I) NITRATE (1:1); (NITRATES) CAS:7631-99-4 RTECS #:WC5600000 Fraction by Wt: <1% Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SILICON COMPOUNDS) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: <0.5% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: <4% Ingred Name:2-BENZOTHIAZOLETHIOL; (MERCAPTOBENZOTHIAZOLE). MFR CAS#2492-26-4 CAS:149-30-4 RTECS #:DL6475000 Fraction by Wt: <0.5% Ingred Name:1H-BENZOTRIAZOLE, METHYL-; (TOLYLTRIAZOLE) CAS:29385-43-1 RTECS #:DM1300000 Fraction by Wt: <0.5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CONT W/THIS PROD CAUSES EYE/SKIN IRRIT. INHAL OF VAP/MISTS MAY BE IRRIT TO RESP TRACT. INGEST OF ABOUT 100 ML OF ETHYLENE GLYCOL MAY RSLT IN ACUTE POISONING, WHICH IS CHARACT BY SEV ABDOM DISTURB, CNS DEPRESS, & POSS RESP/RENAL FAILURE. PRLNG INHAL OF VAPS MAY CAUSE UNCON/INCREASED LYMPHOCYTE COUNTS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CHRONIC: OVEREXP MAY LEAD TO LIVER DEGENERATION & SEVERE RENAL DAMAGE. ANIMAL STUDIES INDICATE THAT ETHYLENE GLYCOL MAY BE EMBRYOTOXIC/TERATOGENIC BY ORAL/INHALATION ROUTES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/FLOWING WATER FOR AT LEAST 15 MIN. GET MED ATTN. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. REMOVE CONTAMD CLTHG/WASH BEFORE REUSE. IF IRRIT DEVELOPS, CONSULT MD. INGEST: IF SWALLOWED, DI LUTE W/WATER & IMMED INDUCE VOMIT. NEVER GIVE FLUIDS OR INDUCE VOMIT IF VICTIM IS UNCON/HAVING CONVL. GET IMMED MED ATTN. INHAL: MOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY, & GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:250F,121C Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2 OR DRY CHEMICAL EXTINGUISHING MEDIA. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID BREATHING VAPORS OR FUMES OF HEATED OR BURNING PRODUCT. Unusual Fire/Explosion Hazard:VAPORS FROM HEATED (ABOVE FLASH POINT) PRODUCT MAY TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:SPILLS SHOULD BE CONTAINED, SOLIDIFIED, AND PLACED IN SUITABLE CONTAINERS FOR DISPOSAL. THIS MATERIAL IS NOT REGULATED UNDER RCRA OR CERCLA (SUPERFUND). CLEAN UP QUICKLY AS SPILLS ARE A SLIPPING HAZAR D. WASH AWAY SMALL AMOUNTS W/COOL WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTRS CLOSED. ALL LABELED PRECAUTIONS MUST BE OBSERVED WHEN HANDLING, STORING & TRANSPORTING EMPTY CONTRS DUE TO PROD RESIDUES. Other Precautions:DO NOT REUSE THIS CONTR UNLESS IT IS PROFESSIONALLY CLEANED/RECONDITIONED. THIS PROD IS SOLD SOLELY FOR USE BY INDUSTRIAL INSTITUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VAPORS OR MISTS ARE GENERATED, WEAR NIOSH/MSHA APPROVED ORGANIC VAPOR/MIST RESPIRATOR. Ventilation:LOCAL EXHAUST TO CONTROL VAPORS OR MISTS. Protective Gloves:RUBBER GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:USE APRON AND SHOES. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH BEFORE REUSE. Supplemental Safety and Health WASTE DISP METH: UNAUTHORIZED REUSE. SPILL MATL, UNUSED CONTENTS & EMPTY CONTRS MUST BE DISPOSED OF IN ACCORDANCE W/ LOCAL, STATE AND FEDERAL REGULATIONS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:330F,166C Vapor Pres:18 @ 20C Spec Gravity:1.135 pH:9-11 Solubility in Water:INFINITE Appearance and Odor:GREEN DYED LIQUID, FAINT GLYCOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISP METH: INCIN OR BURY IN LICENSED FACILITY. DO NOT DISCHARGE INTO WATERWAYS. DISCHARGE TO SEWER SYSTEMS W/ PRIOR APPROVALS IS ACCEPTABLE. CONTR DISPOSAL: DISPOSE OF IN LICENSED FACILITY. RECO MMEND CRUSHING OR OTHER MEANS TO PVNT (SUPP DATA) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.