SIGMA CHEMICAL COMPANY -- HYDROCHLORIC ACID SOLUTION 1.0N, 920-1 -- 6810-00N020449
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID SOLUTION 1.0N, 920-1 MSDS Date:12/19/1988 FSC:6810 NIIN:00N020449 === Responsible Party === Company Name:SIGMA CHEMICAL COMPANY Box:14508 City:ST. LOUIS State:MO ZIP:63178 Info Phone Num:800-325-3010 314-771-5750 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III) CAS:7647-01-0 RTECS #:MW4025000 OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:CAUSES BURNS. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION AND EDEMA OF LA RYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. SYMPTOMS OF EXPOSURE MAY INCLUDE (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. CHRONIC:PROLONGED EXPOSURE CAN CAUSE PNEUMONITIS. PULMONARY EDEMA. EFFECTS MAY BE DELAYE D. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:IF SWALLOWED, WASH OUT MOUTH WITH H2O PROVIDED PERSON IS CONSCIOUS. CALL PHYS. SKIN:FLUSH WITH COPIOUS AMOUNTS OF H2O FOR AT LEAST 15 MIN. REMOVE CONTAMINATED CLOTHING & SHOES & CALL PHYS. INHA L:REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL PHYS. EYES:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. ASSURE ADEQUATE FLUSHING BY SEPARATING LIDS WITH FINGERS. CALL PHYS. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES. MIX WITH SOLID SODIUM BICARBONATE, SWEEP UP, PLACE IN BAG AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMP LETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAP. CAUSES BURNS. HARMFUL BY INHAL/IN CONT W/SKIN/IF SWALLOWED. Other Precautions:THIS PRODUCE IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES. Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD. Other Protective Equipment:WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:TAKE OFF IMMED ALL CONTAMINATED CLOTHING. IN CASE OF CONTACT WITH EYES, RINSE IMMED WITH PLENTY OF H2O/SEEK MED ADVICE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:C1 Appearance and Odor:CLEAR COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX MATERIAL WITH COMBUSTIBLE SOLVENT AND BURN IN CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.