AIR PRODUCTS AND CHEMICALS INC. -- AMMONIA -- 6830-00-169-0777
===================== Product Identification ===================== Product ID:AMMONIA MSDS Date:12/01/1992 FSC:6830 NIIN:00-169-0777 === Responsible Party === Company Name:AIR PRODUCTS AND CHEMICALS INC. Address:7201 HAMILTON BLVD City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Info Phone Num:215-481-4911 Emergency Phone Num:800-523-9374 CAGE:00742 === Contractor Identification === Company Name:AIR PRODUCTS AND CHEMICALS INC Address:7201 HAMILTON BLVD Box:City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Phone:800-345-3148/ 800-752-1597 CAGE:00742 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIA (SARA III) CAS:7664-41-7 RTECS #:BO0875000 Fraction by Wt: >99% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:25 PPM/35 STEL; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50=7338PPMS 1HR RAT Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:IRRIT/CHEM BURNS.INHAL:IRRIT NOSE/THROAT/LUNGS.ACUTE DAMAGE TO RESP SYS @1000PPM.BRONCHOSPASM FRM UPPER AIRWAY DAMAGE;FLUID BUILDUP & HEMORRHAGE FRM LOWER AIRWAY DAMAGE.EYE:MODERATE/SEVE IRRIT.SKIN:VA P CAUSES IRRIT/BURNS.CONTACT W/LIQ CAUSES TISSUE FREEZING ACCOMPANIED BY CORR CAUSTIC ACTION/DEHYDRATION.>300PPM CNS EFF Explanation of Carcinogenicity:PER MSDS:NOT LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY NTP/IARC/OSHA. Effects of Overexposure:IRRITATION & TEARING OF EYES, COUGHING, DIFFICULTY IN BREATHING, HEADACHE, & NAUSEA. CRYOGENIC BURNS OR FROSTBITE FROM LIQUID CONTACT W/SKIN OR CLOTHING. Medical Cond Aggravated by Exposure:TARGET ORGANS:LUNGS, EYES, SKIN. CONDITIONS GENERALLY AGGRAVATED BY EXPOUSRE INCLUDE ASTHMA, CHRONIC RESPIRATORY DISEASE (E.G., EMPHYSEMA) AND EYE DISEASE. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO UNCONTAMINATED AREA.IF NOT BREATHING GIVE ART RESP.IF BREATHING DIFFI GIVE OXYGEN.SEEK MED ATTN;CONTINUE ADMINISTRATION OF OXYGEN.EYE:FLUSH W/LARGE QUANT OF WATER.CONSULT PHYSICIAN.SKIN: GAS:FLUSH W/LG QUANT OF WATER.LIQ:FLUSHW/LUKEWARM WATER.DO NOT USE HOT WATER.TREAT FOR FROSTBITE/CAUSTIC BURNS.CONSULT PHYSICIAN.DR NOTE:BRONCHOSPASM MAY BE TREATED W/USE OF BRONCHODIALATOR(SUPPLEME) ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:1562F Lower Limits:15 Upper Limits:28 Extinguishing Media:WATER. Fire Fighting Procedures:STOP FLOW W/O RISK;UNABLE LET IT BURN OUT.FIGHTFIRE ACCORDING TO TYP OF MATL BURNING.MOVE ADJ CYL AWAY FROM FIRE.COOL CYL W/WATERSPRAY TIL WELL AFT FIRE IS OUT. Unusual Fire/Explosion Hazard:RUNOFF FROM FIREFIGHTING MAY BE CONTAMIN;CHECK PH.CYL EXPO TO HIGH HEAT/FLAME MAY VENT RAPIDLY/EXPLO.AMMONIA CAN FORM EXPLO COMPDS WHEN COMBINED W/MERCURY. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE EVERYONE.INCREASE VENTILATION.USE APPROPRIATE PROT EQMPT(SCBA,CHEM RESISTANT SUIT).REMOVE IGN SOURCES.IF CYL LEAK CALL AIR PROD.IF USER LEAK CLS CYL,VENT PRESS,PURGE LINES W/INERT GAS BEF REP AIR.CONTROL VAP W/WATERSPRAY.RUNOFF MAYBE CONTAMI Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE TEMP:<125F.STORE AWAY FRM COMBUST MATL/HEAVILY TRAVELED AREA/EMERGY EXITS/WELL VENTI AREA/PROT FRM WEATHER.AVOID WHERE SALT/CORR MATL ARE STOR Other Precautions:SECURE CYL IN UPRIGHT POSITION.VAL PROT CAPS/VAL OUTLET SEALS SHOULD REMAIN ON CYL WHEN NOT IN USE.SEPARATE FULL/EMPTY CYL.AVOID EXCESSIVE INVENTORY/STORAGE TIME.USE 1ST IN 1ST OUT.VISUALLY INSPECT CY L ROUTINELY.DO NOT DRAG/ROLL/SLIDE CYL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA OR POS PRESSURE AIRLINE W/FULL FACE MASK IN AREAS OF LARGE RELEASE.NIOSH APPROVED RESP IN SMALL RELEASE OWH WHEN THERE'S POTENTIAL FOR EXPO.TOTAL ENCAPSULATING CHEM SUIT MAY BE NECESSARY IN LG RE LEASES. Ventilation:USE HOOD W/FORCED VENTILATION &/OR LOCAL EXHAUST TO KEEP CONCENTRATIONS BELOW 25PPM. Protective Gloves:LEATHER, RUBBER GLOVES. Eye Protection:SAFETY GLASSES, FACESHIELD. Other Protective Equipment:SAF SHOES.CHEMI RESIST OUTER GARMENT/FACESHIELDS/RUBB GLOVES WHEN CONNECT/DISCONNECT CYL. Work Hygienic Practices:COLD TEMP MAY EMBRITTLE PPE MATL CAUSING BREAKAGE/EXPO.LAUNDER CONTAMIN CLOTHING/SHOE PRIOR TO REUSE. Supplemental Safety and Health 1STAID:SUCH AS ALBUTEROL & ANTICHOLINERGIC INHALANT SUCH AS ATROVENT. HANDL/STORAGE:SEE PAMPHLET CGA P-1 "SAFE HANDLING OF COMPRESSED GAS IN CNTR" BY COMPRESSED GASS ASSOC(703-979-0900(.COMPRESSED GAS CYL SHALL NOT BE REFILLED EXCEPT BY QUAL PROD OF COMP GAS;OTHEWRWISE ITS VIOLATION OF FED LAW. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-28F,-33C Melt/Freeze Pt:M.P/F.P Text:-108F,-78C Vapor Pres:129.1PSIA Vapor Density:.044LB/FT3 Spec Gravity:0.593 @70F Solubility in Water:0.848 VOL/VOL @68F Appearance and Odor:COLORLESS, SHARP, STRONG SIMILAR TO SMELLING SALTS READILY DETECTABLE @20PPM. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, COPPER & ZINCE, THEIR ALLOYS, MERCURY, & OXIDIZERS. Stability Condition to Avoid:HIGH TEMPERATURES (>800F). Hazardous Decomposition Products:OXIDES OF NITROGEN. HYDROGEN @ HIGH TEMPERATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T RELEASE LG AMTS TO ATM.NOT MARINE POLLUTANT-49CFR,HM-211.RETURN CYL/UNUSED PROD TO SUPPLIER W/VAL CLSD/OUTLET CAP ON/VAL PROT CAP SECURED.SM AMTS:DISCHARGE INTO H2O(10PARTS H2O/1PART NH3).NEUTRA LIZE/DISPOSE IAW REGS.RQ=100LB,TPQ=500LB,TQ=5000LB Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.