ICI AMERICAS INC -- POOL BREEZE  -- 6850-00N053992
<pre>=====================  Product Identification  =====================

Product ID:POOL BREEZE
MSDS Date:01/20/1993
FSC:6850
NIIN:00N053992
=== Responsible Party ===
Company Name:ICI AMERICAS INC
City:WILMINGTON
State:DE
ZIP:19897
Country:US
Info Phone Num:302-886-3000
Emergency Phone Num:800-327-8633
CAGE:1N759
=== Contractor Identification ===
Company Name:ICI AMERICAS INC. (FILM DIVISION)
Address:NEW MURPHY ROAD AND CONCORD PIKE
Box:City:WILMINGTON
State:DE
ZIP:19897
Country:US
Phone:302-575-3000
CAGE:1N759

=============  Composition/Information on Ingredients  =============

Ingred Name:HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE) 
    (SARA III)
CAS:7778-54-3
RTECS #:NH3485000
Fraction by Wt: 65-75%
OSHA PEL:0.5 PPM (CHLORINE)
ACGIH TLV:0.5 PPM (CHLORINE)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:SODIUM CHLORIDE
CAS:7647-14-5
RTECS #:VZ4725000
Fraction by Wt: 10-20%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CHLORIC ACID, CALCIUM SALT; (CALCIUM CHLORATE)
CAS:10137-74-3
RTECS #:FN9800000
Fraction by Wt: 0-5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CALCIUM CHLORIDE
CAS:10043-52-4
RTECS #:EV9800000
Fraction by Wt: 0-5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CALCIUM HYDROXIDE  OTHER PROT EQPT:  NEOPRENE OR PVC.
CAS:1305-62-0
RTECS #:EW2800000
Fraction by Wt: 0-4%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:5 MG/M3

Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE)
CAS:471-34-1
RTECS #:FF9335000
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:N/K 

Ingred Name:SUPDAT: FOLLOWING INGEST OF THIS POTENTIALLY CORR MATL
    CONTRAINDICATES THE INDUCTION OF VOMIT IN TREATMENT OF (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: INTOXICATION. SIMILARLY, GASTRIC LAVAGE IS NOT
    ADVISED EXCEPT BY SOME AUTHORS WHO RECOM ITS USE W/IN ONE (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: HOUR OF INGESTION. IN CASES OF SEVERE ESOPHAGEAL
    CHEM CORR, GENERAL SUPPORTIVE MEASURES W/SCRUPULOUS (ING 10)
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED

Ingred Name:ING 9: MONITORING OF GAS EXCHANGE, ACID-BASE BALANCE,
    ELECTROLYTES & FLUID INTAKE ARE OF HIGH SIGNIFICANCE. THE (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: USE OF STEROIDS IS CONTROVERSIAL. IT HAS BEEN FOUND
    USEFUL IN DELAYING STRICTURE FORMATION BUT HAS ALSO (ING 12)
RTECS #:9999999ZZ
Other REC Limits:N/K+

Ingred Name:ING 11: BEEN IMPLICATED IN THE DEVELOPMENT OF PERITONEAL
    SIGNS.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: PROD IS HAZ WASTE, NUMBER D001, UNDER
    RCRA. DISPOSE OF IN A FACILITY PERMITTED FOR HAZ WASTE.
RTECS #:9999999ZZ

Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL, RAT) > 850 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INGEST: THIS MATERIAL IS CLASSIFIED AS
    SLIGHTLY TOXIC. IRRITATION OR CHEMICAL BURNS OF MOUTH, PHARYNX,
    ESOPHAGUS & STOMACH CAN DEVELOP FOLLOWING INGESTION. INJURY MAY BE
    SEVERE & CAUSE DEATH. EYES: CA N INDUCE CHEMICAL BURNS ON CONTACT.
    SKIN: WILL PROBABLY SEVERELY IRRITATE OR BURN SKIN. WILL PROBABLY
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: NOT BE ABSORBED THROUGH SKIN. INHAL:
    DATA NOT AVAILABLE ON THIS MATERIAL. PARTICULATES OF THIS MATERIAL
    WILL PROBABLY IRRITATE RESPIRATORY PASSAGES. PRODUCT HAS POTENTIAL
    TO BE IMMEDIATELY D ANGEROUS TO LIFE/HEALTH. INHALATION OF HIGH
    CONCENTRATIONS CAN RESULT IN PERMANENT LUNG DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:SKIN: WASH MATL OFF SKIN W/SOAP & FLUSH W/PLENTY OF WATER FOR
    AT LEAST 15 MIN. GET MED ATTN. WASH CONTAMD CLTHG & DECONTAM
    FOOTWEAR BEFORE REUSE. EYES: IMMED FLUSH W/PLENTY OF WATER. AFTER
    INITIAL FLU SHING, REMOVE ANY CNTCT LENSES & CONTINUE FLUSHING FOR
    AT LEAST 15 MIN. HAVE EYES EXAMINED & TREATED BY MED PERS. INGEST:
    GIVE 1 OR 2 GLASSES OF WATER TO DRINK & REFER TO MED PERS. (NEVER
    (SUPDAT)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. DO
    NOT USE DRY PWDR FIRE EXTINGUISHERS CONTAINING MONO-AMMONIUM
    PHOSPHATE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:OXIDIZER MAY RELEASE CHLORINE, A
    CORROSIVE AND FLAMMABLE GAS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR SKIN, EYE & RESPIRATORY PROTECTION DURING
    CLEANUP. KEEP OUT OF SEWERS AND DRAINS. SWEEP UP AND RECOVER OR MIX
    MATERIAL WITH A MOIST ABSORBENT AND SHOVEL INTO A CHEMICAL WASTE
    CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP TIGHTLY SEALED. STORE IN COOL,
    DRY, WELL VENTILATED AREA, AWAY FROM FLAMMABLE, COMBUSTIBLE OR
    OTHER MATERIALS CAPABLE OF OXIDATION.
Other Precautions:FOLLOW PROCEDURES SPECIFIED IN THE NATIONAL
    PROTECTION ASSOCIATION CODES & STANDARDS FOR HANDLING OXIDIZING
    MATERIALS. PREVENT SKIN & EYE CONTACT. OBSERVE OSHA PEL
    LIMITATIONS. AVOID BREATHING PARTICU LATES.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF NEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR
    WITH CHLORINE CARTRIDGES AND DUSTS/MISTS FILTER.
Ventilation:USE VENTILATION ADEQUATE TO MAINTAIN SAFE LEVELS.
Protective Gloves:NEOPRENE OR PVC GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 14)
Other Protective Equipment:EMER EYE WASH AND DELUGE SHOWER WHICH MEETS
    ANSI DESIGN CRITERIA . USE BOOTS AND IMPERVIOUS APRON OF (ING 5)
Work Hygienic Practices:MINIMIZE EXPOSURE LIMITS IN ACCORDANCE WITH
    GOOD HYGIENE PRACTICE.
Supplemental Safety and Health
PH: 10.5-11.5 @ 25C. MATL TO AVOID: CONTAINING CMPDS, CORR,
    FLAMM/COMBUST MATLS. GLYCEROL, DIGLOMONOMETHYL ETHER OR PHENOL MAY
    CAUSE IGNIT W/GENERATION OF IRRITANT SMOKE. FIRST AID PROC: GIVE
    ANYTHING  BY MOUTH TO UNCON PERSON). INHAL: REMOVE TO FRESH AIR.
    CONSULT MED PERS IMMED. NOTE TO MD: MUCOSAL INJURY (ING 7)

==================  Physical/Chemical Properties  ==================

HCC:D2
pH:SUPDAT
Solubility in Water:SOLUBLE 18% @ 25C
Appearance and Odor:WHITE FREE FLOWING POWDER; CHLORINE-LIKE ODOR.
Percent Volatiles by Volume:NEGLIG

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
CNTNR MUST BE CLEAN & FREE OF ORG RESIDUES. ACIDS, OTHER ORG SULFIDES,
    OXIDIZERS, ALL CORR LIQS, NITROGEN (SUPDAT)
Stability Condition to Avoid:MAY DECOMPOSE IF EXPOSED TO HEAT OR DIRECT
    SUNLIGHT.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: HALOGEN, HALOGEN
    ACIDS, POSSIBLE TRACE AMOUNTS OF CARBONYL HALIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FED, STATE & LOC REGS .
    MATL IS TOX TO FISH. DO NOT CONTAM WATERWAYS BY CLEANING OF
    EQUIP/BY DISP OF WASTES. UNTREATED EFFLUENT SHOULD NOT BE
    DISCHARGED WHERE IT WILL DRAI N INTO LAKES, STREAMS OR PONDS.
    DISCARDED (ING 13)

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